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MATERIAL SAFETY DATA SHEET     

 

1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION

 

Trade Name      DETERGENT DISINFECTANT PUMP SPRAY

Manufacturer     APDC, Inc.

5047 Martin Luther King Frwy

Fort Worth, TX 76119

 

Telephone Numbers - 24 Hour Emergency Assistance                             Telephone Numbers - General Assistance

Medical  - 800-228-5635                                                 General -(817) 395-0120

Chemtrec  - 800-424-9300

Chemtrec Int'l  - 703-527-3887

                                                                                   

2 HAZARDS IDENTIFICATION

 

Emergency Overview

Clear liquid,

May cause irritation to eyes and skin.

 

Health Effects: Eyes

This product may cause irritation to the eyes.

 

Health Effects: Skin

This product may cause irritation to the skin.

 

Health Effects: Inhalation

Exposure via inhalation not likely. High vapor or aerosol mist concentrations may be irritating to the nose,

throat and upper respiratory tract.

 

Health Effects: Ingestion

Ingestion may cause transient irritation of throat, stomach and gastrointestinal tract. Ingestion of large

amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea.

 

3 COMPOSITION / INFORMATION ON INGREDIENTS

 

Ingredient Name                                                                                                                 CAS Number                       Percent

 

_Diethylene glycol monobutyl ether                                                                                                112-34-5                               8 %

 

_Alkyl dimethyl benzyl ammonium chloride (C12-18)                                                                68391-01-5                           0.105 %

 

_Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl ammonium chloride                                 85409-23-0                           0.105 %

(Alt CAS 68956-79-6)                                                                                                        

 

4 FIRST AID MEASURES

 

Eyes

Immediately flush eyes with water for at least 15 minutes while holding eyelids open. If irritation persists get

medical attention.

 

Skin

Immediately take off all contaminated clothing.Wash contaminated clothing before reuse.For skin contact,

flush with large amounts of water. If irritation persists, get medical attention.

 

Inhalation

If symptoms are experienced, remove source of contamination or move victim to fresh air.If symptoms

persist, get medical attention. If not breathing, give artificial respiration, preferably mouth-to-mouth. If

breathing is difficult, give oxygen. Seek medical attention.

 

Ingestion

Do not induce vomiting.If ingestion of a large amount does occur, seek medical attention.Never give

anything by mouth to a victim who is unconscious or is having convulsions.

 

Notes to Physician

If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Treat the

affected person appropriately.

 

5 FIRE FIGHTING MEASURES

 

Flash Point (> 93.9 °C), > 201 F PMCC

 

Extinguishing Media

Use appropriate methods for combatting the surrounding fire.

 

Fire Fighting Equipment / Instructions

Firefighters should wear full fire-fighting turn-out gear (full Bunker gear) including NIOSH-approved

self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive

pressure mode.

 

6 ACCIDENTAL RELEASE MEASURES

 

SPILL AND LEAK PROCEDURES

Emergency Action:

Isolate spill or leak area immediately. Keep unauthorized personnel away.Stay upwind.Keep out of low

areas.Ventilate closed spaces before entering.

Do not touch or walk through spilled material. Wear appropriate personal protective equipment during

cleanup.Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers

for later disposal. Large Spills: Dike ahead of liquid spill for later disposal.

Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other

waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System

(NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not

discharge effluent containing this product to sewer systems without previously notifying the local sewage

treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.

 

7 HANDLING & STORAGE

 

Handling Procedures

Avoid contact with skin and eyes.Avoid breathing vapors or mists of this product.Wash thoroughly after

handling.As with all chemicals, good industrial hygiene practices should be followed when handling this

material.

 

Storage Procedures

Store in a dry, well-ventilated area.Avoid freezing or excessive heat.

DO NOT CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR DISPOSAL.

 

Engineering Controls

Use with adequate ventilation.

 

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Personal Protective Equipment: Eyes/Face

Wear safety glasses with side shields.

 

Personal Protective Equipment: Skin

Use impervious gloves.Wear suitable protective clothing.

 

Personal Protective Equipment: Respiratory

Under normal conditions, respirator is not normally required.If vapors are present or irritation is experienced,

NIOSH approved respiratory protection for ammoniacal vapors should be worn.

 

Personal Protective Equipment: General

Eye wash fountain and emergency showers are recommended.

_Diethylene glycol monobutyl ether 112-34-5

NIOSH - Health Standards - Exposure Limits reduce exposure to lowest feasible concentration

 

9 PHYSICAL & CHEMICAL PROPERTIES

 

Flash Point                 (> 93.9 °C),       > 201 F PMCC

Boiling Point                (> 100 °C),        > 212 F

Specific Gravity            (1.007 g/ml),     8.38 lb/gal

Solubility in Water Complete

pH Value 11.7

Freezing Point (> 0 °C), > 32 F

Appearance and Odor

Clear liquid,


Chemical Stability

Stable under normal conditions

 

Conditions to Avoid

Avoid strong oxidizing agents.

 

Incompatibility

Strong acids, alkalies and oxidizing agents.

 

Hazardous Decomposition

Upon decomposition, this product may yield oxides of nitrogen and ammonia.

 

Hazardous Polymerization

Will not occur.

 

10 TOXICOLOGICAL INFORMATION

 

Carcinogenicity

Not listed as carcinogenic according to IARC, NTP or OSHA.

_Tetra sodium ethylenediamine tetra acetic acid (Na4 EDTA) 64-02-8

Toxicology Data - Selected LD50s and LC50s Oral LD50 Rat: 1658 mg/kg

_Water 7732-18-5

Toxicology Data - Selected LD50s and LC50s Oral LD50 Rat: >90 mL/kg

_Diethylene glycol monobutyl ether 112-34-5

Toxicology Data - Selected LD50s and LC50s Oral LD50 Rat: 3384 mg/kg; Dermal LD50 Rabbit: 2700 mg/kg

 

11 ECOLOGICAL INFORMATION

 

Ecotoxicity

Toxic to fish.Toxic to aquatic organisms.

 

12 DISPOSAL CONSIDERATIONS

 

Disposal Instructions

 

CONTAINER DISPOSAL: Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or

reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by state and

local authorities, by burning. If burned, stay out of smoke. For containers 1 gallon or less: Do not reuse

empty container (bottle, can, bucket). Wrap container and put in trash.

PESTICIDE DISPOSAL - Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide,

spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use

according to label instructions contact your State Pesticide or Environmental Control Agency, or the

Hazardous Waste representative at the nearest EPA Regional Office for guidance.

 

13 TRANSPORT INFORMATION

DOT Proper Shipping Name                                         Refer to bill of lading or container label for DOT or other

transportation hazard classification, if any.

 

14 REGULATORY INFORMATION

_Diethylene glycol monobutyl

ether

112-34-5

CAA (Clean Air Act) - 1990 Hazardous Air                       [present] (includes mono- and di- ethers of Ethylene glycol,

Pollutants                                                                     and Triethylene glycol as specified by referenced formula)

CERCLA/SARA - Section 313 - Emission                        concentration; Chemical Category N230; (applies to

R-(OCH2CH2)n-OR'''' ethers, where n = 1,2, or 3''''; R=alkyl

C7 or less or R = phenyl or alkyl subst. phenyl; R'''' = H or

alkyl C7 or less, or OR'''' consisting of carboxylic acid ester,

sulfate, phosphate, nitrate, or sulfonate)

 

EPA - Designated Generic Categories - Certain               RR-00067-9

Glycol Ethers

TSCA (Toxic Substances Control Act) - Section 4           40 CFR 799.1560

- Chemical Test Rules (40 CFR 79)

 

U.S. Federal Regulations

Ingredient Name                                                                                                 CAS                                        Number Percent

_Diethylene glycol monobutyl ether                                                                                112-34-5                               8 %

_Alkyl dimethyl benzyl ammonium chloride (C12-18)                                                68391-01-5                           0.105 %

_Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl ammonium chloride 85409-23-0                           0.105 %

(Alt CAS 68956-79-6)                                                                                        

 

State Regulations

This product may contain the following ingredient(s) known to the State of California to cause cancer, birth

defects or other reproductive harm:Ethylene Oxide (CAS RN: 75-21-8)Nitrilotriacetic acid (NTA) (CAS RN:

139-13-9)

 

Inventories

This product is considered a pesticide, and is therefore excluded from the United States TSCA Regulations.

There is no calculable reportable quantity (RQ) for this product.

 

Disclaimer

Disclaimer: Nothing contained herein grants or extends a license, express or implied, in connection with

patents, issued or pending, of the manufacturer or others. The information contained herein is based on the

manufacturer's own study and the works of others. The manufacturer makes no warranties, expressed or

implied, as to the accuracy, completeness, or adequacy of the information contained herein. The

manufacturer shall not be held liable (regardless of fault) to the vendee's employees, or anyone for any direct,

special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy

or furnishing of such information.

 

15 OTHER INFORMATION

 

HAZARD RATINGS                   HMIS                            NFPA

Health                                      1                                  1                     

Flammability                            1                                  1

Reactivity                                 0                                  0

PPE                                         X


APDC, Inc. * 5047 Martin Luther King Freeway * Fort Worth, Texas 76119 * Ph# 817-395-0120  * Fax# 817-395-0124